Metal-Organic Framework Based Chromium Terephthalate (MIL-101 Cr) Growth for Carbon Dioxide Capture: A Review

Journal of Advanced Research in Fluid Mechanics and Thermal Sciences
Volume 57, No. 2, May 2019, Pages 158-174

Fayza Yulia1, Nasruddin1,*, Agustino Zulys2, Rizky Ruliandini1

1 Department of of Mechanical Engineering, Faculty of Engineering, University of Indonesia, Depok, 16424, Indonesia
2 Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia, Depok, 16424, Indonesia
*Corresponding author: nasruddin@eng.ui.ac.id

Cite this article
MLA
Fayza, Yulia, et al. "Metal-Organic Framework Based Chromium Terephthalate (MIL-101 Cr) Growth for Carbon Dioxide Capture: A Review." Journal of Advanced Research in Fluid Mechanics and Thermal Sciences 57.2 (2019): 158-174.
APA

Fayza, Y., Nasruddin, Agustino, Z., & Rizky, R.(2019). Metal-Organic Framework Based Chromium Terephthalate (MIL-101 Cr) Growth for Carbon Dioxide Capture: A Review. Journal of Advanced Research in Fluid Mechanics and Thermal Sciences, 57(2), 158-174.
Chicago
Fayza Yulia, Nasruddin, Agustino Zulys, and Rizky Ruliandini."Metal-Organic Framework Based Chromium Terephthalate (MIL-101 Cr) Growth for Carbon Dioxide Capture: A Review." Journal of Advanced Research in Fluid Mechanics and Thermal Sciences. 57, no. 2 (2019): 158-174.
Harvard
Fayza, Y., Nasruddin, Agustino, Z., Rizky, R., 2019. Metal-Organic Framework Based Chromium Terephthalate (MIL-101 Cr) Growth for Carbon Dioxide Capture: A Review. Journal of Advanced Research in Fluid Mechanics and Thermal Sciences 57(2), pp. 158-174.
Vancouver

Fayza Y, Nasruddin, Agustino Z, Rizky R. Metal-Organic Framework Based Chromium Terephthalate (MIL-101 Cr) Growth for Carbon Dioxide Capture: A Review. Journal of Advanced Research in Fluid Mechanics and Thermal Sciences. 2019;57(2): 158-174.

KEYWORDS

MIL-101: CO_2 capture; adsorption; adsorbent characteristics; metal-organic framework

ABSTRACT

Lowering CO_2 emissions and the concentration of greenhouse gasses become major concern to overcome the global warming issue. One method to reduce CO_2 emissions is to implement the carbon capture and storage (CCS). In addition to developing the CCS technology, the investigations on materials that have high gas separation performance and low costs are also widely executed. A new type of crystalline porous material, metal-organic framework (MOF), which consists of metal ions and organic ligands in recent years as a promising type of adsorbent has emerged. MIL-101 Cr which is comprised of trimeric chromium (III) octahedral connected to 1,4-benzenedicarboxylates, one type of MOF, has attracted a lot of attention among researchers to develop the performance of CO_2 adsorption, since this chromium terephthalate has a large pore size (29 and 34 Å) and specific surface area attaining to more than 3,000 m2/g. Thermal stability and moisture resistance of this adsorbent make this material easily modified in post-synthesis, organic functionalization, cation doping, and composite type of MOF. In this study, we review the research and development of the synthesis, functionalization, and modification for the application of CO_2 adsorption in MIL-101 Cr.

REFERENCES

[1] Khattak, M. A., A. A. Arifb, A. Hannanc, F. Syukrid, and H. Hamid. "Design and planning of a nuclear power plant in Malaysia: A feasibility report." Journal of Advanced Research in Applied Sciences and Engineering Technology 3, no. 1 (2016): 67-76.
[2] Obergassel, Wolfgang, Christof Arens, Lukas Hermwille, Nicolas Kreibich, Florian Mersmann, Hermann E. Ott, and Hanna Wang-Helmreich. "Phoenix from the ashes: an analysis of the Paris Agreement to the United Nations Framework Convention on Climate Change; part 1." (2015).
[3] Jamil, M., N. C. Sidik, and MNAW Muhammad Yazid. "Thermal performance of thermosyphon evacuated tube solar collector using TiO2/water nanofluid." J. Adv. Res. Fluid Mech. Therm. Sci 20, no. 1 (2016): 12-29.
[4] Stéphenne, Karl. "Start-up of world's first commercial post-combustion coal fired CCS project: contribution of Shell Cansolv to SaskPower Boundary Dam ICCS project." Energy Procedia 63 (2014): 6106-6110.
[5] Plaza, Jorge M., David Van Wagener, and Gary T. Rochelle. "Modeling CO2 capture with aqueous monoethanolamine." International Journal of Greenhouse Gas Control 4, no. 2 (2010): 161-166.
[6] Aziz, Abdul Shukor Abdul, Latifah Abd Manaf, Hasfalina Che Man, and Nadavala Siva Kumar. "Column dynamic studies and breakthrough curve analysis for Cd (II) and Cu (II) ions adsorption onto palm oil boiler mill fly ash (POFA)." Environmental Science and Pollution Research 21, no. 13 (2014): 7996-8005.
[7] Ruthven, Douglas M. Principles of adsorption and adsorption processes. John Wiley & Sons, 1984.
[8] Dantas, Tirzhá LP, Francisco Murilo T. Luna, Ivanildo J. Silva Jr, Diana CS de Azevedo, Carlos A. Grande, Alírio E. Rodrigues, and Regina FPM Moreira. "Carbon dioxide–nitrogen separation through adsorption on activated carbon in a fixed bed." Chemical Engineering Journal 169, no. 1-3 (2011): 11-19.
[9] Chowdhury, Pradip, Chaitanya Bikkina, and Sasidhar Gumma. "Gas adsorption properties of the chromium-based metal organic framework MIL-101." The Journal of Physical Chemistry C 113, no. 16 (2009): 6616-6621.
[10] Férey, Gerard, Caroline Mellot-Draznieks, Christian Serre, Franck Millange, Julien Dutour, Suzy Surblé, and Irena Margiolaki. "A chromium terephthalate-based solid with unusually large pore volumes and surface area." Science 309, no. 5743 (2005): 2040-2042.
[11] Hong, Do?Young, Young Kyu Hwang, Christian Serre, Gerard Ferey, and Jong?San Chang. "Porous chromium terephthalate MIL?101 with coordinatively unsaturated sites: surface functionalization, encapsulation, sorption and catalysis." Advanced Functional Materials 19, no. 10 (2009): 1537-1552.
[12] Kobielska, Paulina A., Ashlee J. Howarth, Omar K. Farha, and Sanjit Nayak. "Metal–organic frameworks for heavy metal removal from water." Coordination Chemistry Reviews 358 (2018): 92-107.
[13] Zhang, Yin, Jun Guo, Lin Shi, Yanfei Zhu, Ke Hou, Yonglong Zheng, and Zhiyong Tang. "Tunable chiral metal organic frameworks toward visible light–driven asymmetric catalysis." Science advances 3, no. 8 (2017): e1701162.
[14] Cotton, A.F., et al., Advanced inorganic chemistry. 1999: Wiley.
[15] Noro, Shin-ichiro, Susumu Kitagawa, Tomoyuki Akutagawa, and Takayoshi Nakamura. "Coordination polymers constructed from transition metal ions and organic N-containing heterocyclic ligands: Crystal structures and microporous properties." Progress in Polymer Science 34, no. 3 (2009): 240-279.
[16] Bae, Youn-Sang, Omar K. Farha, Joseph T. Hupp, and Randall Q. Snurr. "Enhancement of CO 2/N 2 selectivity in a metal-organic framework by cavity modification." Journal of Materials Chemistry 19, no. 15 (2009): 2131-2134.
[17] Farha, Omar K., Ibrahim Eryazici, Nak Cheon Jeong, Brad G. Hauser, Christopher E. Wilmer, Amy A. Sarjeant, Randall Q. Snurr, SonBinh T. Nguyen, A. O?zgu?r Yazayd?n, and Joseph T. Hupp. "Metal–organic framework materials with ultrahigh surface areas: is the sky the limit?." Journal of the American Chemical Society 134, no. 36 (2012): 15016-15021.
[18] Howarth, Ashlee J., Aaron W. Peters, Nicolaas A. Vermeulen, Timothy C. Wang, Joseph T. Hupp, and Omar K. Farha. "Best practices for the synthesis, activation, and characterization of metal–organic frameworks." Chemistry of Materials 29, no. 1 (2016): 26-39.
[19] Bauer, Sebastian, and Norbert Stock. "Implementation of a Temperature?Gradient Reactor System for High?Throughput Investigation of Phosphonate?Based Inorganic–Organic Hybrid Compounds." Angewandte Chemie International Edition 119, no. 36 (2007): 6981-6984
[20] Sun, Yujia, and Hong-Cai Zhou. "Recent progress in the synthesis of metal–organic frameworks." Science and technology of advanced materials 16, no. 5 (2015): 054202.
[21] Jhung, Sung Hwa, Jin-Ho Lee, Ji Woong Yoon, Jin-Soo Hwang, Sang-Eon Park, and Jong-San Chang. "Selective crystallization of CoAPO-34 and VAPO-5 molecular sieves under microwave irradiation in an alkaline or neutral condition." Microporous and mesoporous materials 80, no. 1-3 (2005): 147-152.
[22] Hwang, Young Kyu, Jong?San Chang, Sang?Eon Park, Dae Sung Kim, Young?Uk Kwon, Sung Hwa Jhung, Jin?Soo Hwang, and Min Seok Park. "Microwave fabrication of MFI zeolite crystals with a fibrous morphology and their applications." Angewandte Chemie International Edition 117, no. 4 (2005): 562-566.
[23] Jhung, Sung Hwa, Jin Ho Lee, and Jong San Chang. "Microwave synthesis of a nanoporous hybrid material, chromium trimesate." Bulletin of the Korean Chemical Society26, no. 6 (2005): 880-881.
[24] Jhung, Sung Hwa, J?H. Lee, Ji Woong Yoon, Christian Serre, Gérard Férey, and J?S. Chang. "Microwave synthesis of chromium terephthalate MIL?101 and its benzene sorption ability." Advanced Materials 19, no. 1 (2007): 121-124.
[25] Seo, You-Kyong, Geeta Hundal, In Tae Jang, Young Kyu Hwang, Chul-Ho Jun, and Jong-San Chang. "Microwave synthesis of hybrid inorganic–organic materials including porous Cu3 (BTC) 2 from Cu (II)-trimesate mixture." Microporous and Mesoporous Materials 119, no. 1-3 (2009): 331-337.
[26] Horcajada, Patricia, Christian Serre, María Vallet?Regí, Muriel Sebban, Francis Taulelle, and Gérard Férey. "Metal–organic frameworks as efficient materials for drug delivery." Angewandte Chemie International Edition 45, no. 36 (2006): 5974-5978.
[27] Choi, Jung-Sik, Won-Jin Son, Jahoen Kim, and Wha-Seung Ahn. "Metal–organic framework MOF-5 prepared by microwave heating: factors to be considered." Microporous and Mesoporous Materials 116, no. 1-3 (2008): 727-731.
[28] Ni, Zheng, and Richard I. Masel. "Rapid production of metal? organic frameworks via microwave-assisted solvothermal synthesis." Journal of the American Chemical Society 128, no. 38 (2006): 12394-12395.
[29] Lee, Yu-Ri, Jun Kim, and Wha-Seung Ahn. "Synthesis of metal-organic frameworks: A mini review." Korean Journal of Chemical Engineering 30, no. 9 (2013): 1667-1680.
[30] Martinez Joaristi, Alberto, Jana Juan-Alcañiz, Pablo Serra-Crespo, Freek Kapteijn, and Jorge Gascon. "Electrochemical synthesis of some archetypical Zn2+, Cu2+, and Al3+ metal organic frameworks." Crystal Growth & Design 12, no. 7 (2012): 3489-3498.
[31] Baig, RB Nasir, and Rajender S. Varma. "Alternative energy input: mechanochemical, microwave and ultrasound-assisted organic synthesis." Chemical Society Reviews 41, no. 4 (2012): 1559-1584.
[32] Friš?i?, Tomislav, and László Fábián. "Mechanochemical conversion of a metal oxide into coordination polymers and porous frameworks using liquid-assisted grinding (LAG)." CrystEngComm 11, no. 5 (2009): 743-745.
[33] Wu, Hao, and Qiang Li. "Application of mechanochemical synthesis of advanced materials." Journal of Advanced Ceramics 1, no. 2 (2012): 130-137.
[34] Leighton, T., The Acoustic Bubble (Academic, London, 1994). Google Scholar: p. 1-613.
[35] Stock, Norbert, and Shyam Biswas. "Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites." Chemical reviews112, no. 2 (2011): 933-969.
[36] Yang, Jiangfeng, Qiang Zhao, Jinping Li, and Jinxiang Dong. "Synthesis of metal–organic framework MIL-101 in TMAOH-Cr (NO3) 3-H2BDC-H2O and its hydrogen-storage behavior." Microporous and Mesoporous Materials 130, no. 1-3 (2010): 174-179.
[37] Nourian, Maryam, Farnaz Zadehahmadi, Reihaneh Kardanpour, Shahram Tangestaninejad, Majid Moghadam, Valiollah Mirkhani, Iraj Mohammadpoor-Baltork, and Mehrnaz Bahadori. "Chemical fixation of carbon dioxide catalyzed by magnetically recoverable NH2-MIL-101 (Al) as an elegant nanoreactor." Catalysis Communications 94 (2017): 42-46.
[38] Seoane, Beatriz, Carlos Téllez, Joaquín Coronas, and Claudia Staudt. "NH2-MIL-53 (Al) and NH2-MIL-101 (Al) in sulfur-containing copolyimide mixed matrix membranes for gas separation." Separation and Purification Technology 111 (2013): 72-81.
[39] Teo, How Wei Benjamin, Anutosh Chakraborty, and Sibnath Kayal. "Evaluation of CH4 and CO2 adsorption on HKUST-1 and MIL-101 (Cr) MOFs employing Monte Carlo simulation and comparison with experimental data." Applied Thermal Engineering 110 (2017): 891-900.
[40] Dresden, T.U., MIL-101 Cr. Highly Porous Metal-Organic Framework.
[41] Samokhvalov, A., Adsorption on Mesoporous Metal-Organic Frameworks in Solution for Clean Energy, Environment and Healthcare. 2017: CRC Press.
[42] Demessence, Aude, Patricia Horcajada, Christian Serre, Cédric Boissière, David Grosso, Clément Sanchez, and Gérard Férey. "Elaboration and properties of hierarchically structured optical thin films of MIL-101 (Cr)." Chemical Communications 46 (2009): 7149-7151.
[43] Low, John J., Annabelle I. Benin, Paulina Jakubczak, Jennifer F. Abrahamian, Syed A. Faheem, and Richard R. Willis. "Virtual high throughput screening confirmed experimentally: porous coordination polymer hydration." Journal of the American Chemical Society 131, no. 43 (2009): 15834-15842.
[44] Küsgens, Pia, Marcus Rose, Irena Senkovska, Heidrun Fröde, Antje Henschel, Sven Siegle, and Stefan Kaskel. "Characterization of metal-organic frameworks by water adsorption." Microporous and Mesoporous Materials 120, no. 3 (2009): 325-330.
[45] Bhattacharjee, Samiran, Chao Chen, and Wha-Seung Ahn. "Chromium terephthalate metal–organic framework MIL-101: synthesis, functionalization, and applications for adsorption and catalysis." RSC Advances 4, no. 94 (2014): 52500-52525.
[46] Liang, Zhijian, Marc Marshall, Chun Hin Ng, and Alan L. Chaffee. "Comparison of conventional and HF-free-synthesized MIL-101 for CO2 adsorption separation and their water stabilities." Energy & Fuels 27, no. 12 (2013): 7612-7618.
[47] Jiang, Dongmei, Andrew D. Burrows, Robben Jaber, and Karen J. Edler. "Facile synthesis of metal–organic framework films via in situ seeding of nanoparticles." Chemical Communications 48, no. 41 (2012): 4965-4967.
[48] Jiang, Dongmei, Andrew D. Burrows, Yuli Xiong, and Karen J. Edler. "Facile synthesis of crack-free metal–organic framework films on alumina by a dip-coating route in the presence of polyethylenimine." Journal of Materials Chemistry A 1, no. 18 (2013): 5497-5500.
[49] Khan, Nazmul Abedin, In Joong Kang, Hwi Young Seok, and Sung Hwa Jhung. "Facile synthesis of nano-sized metal-organic frameworks, chromium-benzenedicarboxylate, MIL-101." Chemical engineering journal 166, no. 3 (2011): 1152-1157.
[50] Kim, Jun, Yu-Ri Lee, and Wha-Seung Ahn. "Dry-gel conversion synthesis of Cr-MIL-101 aided by grinding: high surface area and high yield synthesis with minimum purification." Chemical communications 49, no. 69 (2013): 7647-7649.
[51] Pourebrahimi, Sina, and Mohammad Kazemeini. "A kinetic study of facile fabrication of MIL-101 (Cr) metal-organic framework: Effect of synthetic method." Inorganica Chimica Acta 471 (2018): 513-520.
[52] Pourebrahimi, Sina, Mohammad Kazemeini, and Leila Vafajoo. "Embedding graphene nanoplates into MIL-101 (Cr) pores: synthesis, characterization, and CO2 adsorption studies." Industrial & Engineering Chemistry Research 56, no. 14 (2017): 3895-3904.
[53] Qasem, Naef AA, Najam U. Qadir, Rached Ben-Mansour, and Syed AM Said. "Synthesis, characterization, and CO2 breakthrough adsorption of a novel MWCNT/MIL-101 (Cr) composite." Journal of CO2 Utilization 22 (2017): 238-249.
[54] Huang, Chan-Yuan, Ming Song, Zhi-Yuan Gu, He-Fang Wang, and Xiu-Ping Yan. "Probing the adsorption characteristic of metal–organic framework MIL-101 for volatile organic compounds by quartz crystal microbalance." Environmental science & technology 45, no. 10 (2011): 4490-4496.
[55] Jiang, Dongmei, Andrew D. Burrows, and Karen J. Edler. "Size-controlled synthesis of MIL-101 (Cr) nanoparticles with enhanced selectivity for CO 2 over N 2." CrystEngComm 13, no. 23 (2011): 6916-6919.
[56] Huang, Xiao-Xian, Ling-Guang Qiu, Wang Zhang, Yu-Peng Yuan, Xia Jiang, An-Jian Xie, Yu-Hua Shen, and Jun-Fa Zhu. "Hierarchically mesostructured MIL-101 metal–organic frameworks: supramolecular template-directed synthesis and accelerated adsorption kinetics for dye removal." CrystEngComm 14, no. 5 (2012): 1613-1617.
[57] Yang, Le-Ting, Ling-Guang Qiu, Sheng-Mei Hu, Xia Jiang, An-Jian Xie, and Yu-Hua Shen. "Rapid hydrothermal synthesis of MIL-101 (Cr) metal–organic framework nanocrystals using expanded graphite as a structure-directing template." Inorganic Chemistry Communications 35 (2013): 265-267.
[58] Chen, Heng, Shaoyun Chen, Xingzhou Yuan, and Yongchun Zhang. "Facile synthesis of metal-organic framework MIL-101 from 4-NIm–Cr (NO3) 3–H2BDC-H2O." Materials Letters 100 (2013): 230-232.
[59] Zhao, Tian, Song-He Li, Ling Shen, Yong Wang, and Xiao-Yu Yang. "The sized controlled synthesis of MIL-101 (Cr) with enhanced CO2 adsorption property." Inorganic Chemistry Communications 96 (2018): 47-51.
[60] Zhao, Zhenxia, Xuemei Li, Sisi Huang, Qibin Xia, and Zhong Li. "Adsorption and diffusion of benzene on chromium-based metal organic framework MIL-101 synthesized by microwave irradiation." Industrial & Engineering Chemistry Research 50, no. 4 (2011): 2254-2261.
[61] Llewellyn, Philip L., Sandrine Bourrelly, Christian Serre, Alexandre Vimont, Marco Daturi, Lomig Hamon, Guy De Weireld et al. "High uptakes of CO2 and CH4 in mesoporous metal? organic frameworks mil-100 and mil-101." Langmuir24, no. 14 (2008): 7245-7250.
[62] Xian, Shikai, Junjie Peng, Zhijuan Zhang, Qibin Xia, Haihui Wang, and Zhong Li. "Highly enhanced and weakened adsorption properties of two MOFs by water vapor for separation of CO2/CH4 and CO2/N2 binary mixtures." Chemical Engineering Journal 270 (2015): 385-392.
[63] Montazerolghaem, Maryam, Seyed Foad Aghamiri, Mohammad Reza Talaie, and Shahram Tangestaninejad. "A comparative investigation of CO2 adsorption on powder and pellet forms of MIL-101." Journal of the Taiwan Institute of Chemical Engineers 72 (2017): 45-52.
[64] Liu, Qing, Liqi Ning, Shudong Zheng, Mengna Tao, Yao Shi, and Yi He. "Adsorption of carbon dioxide by MIL-101 (Cr): Regeneration conditions and influence of flue gas contaminants." Scientific reports 3 (2013): 2916.
[65] Hong, Wan Yun, Semali P. Perera, and Andrew D. Burrows. "Manufacturing of metal-organic framework monoliths and their application in CO2 adsorption." Microporous and Mesoporous Materials 214 (2015): 149-155.
[66] Ye, Sheng, Xin Jiang, Lin-Wei Ruan, Bei Liu, Yi-Min Wang, Jun-Fa Zhu, and Ling-Guang Qiu. "Post-combustion CO2 capture with the HKUST-1 and MIL-101 (Cr) metal–organic frameworks: Adsorption, separation and regeneration investigations." Microporous and Mesoporous Materials 179 (2013): 191-197.
[67] Chen, Chong, Nengjie Feng, Qirui Guo, Zhong Li, Xue Li, Jing Ding, Lei Wang, Hui Wan, and Guofeng Guan. "Template-directed fabrication of MIL-101 (Cr)/mesoporous silica composite: Layer-packed structure and enhanced performance for CO2 capture." Journal of colloid and interface science 513 (2018): 891-902.
[68] Kayal, Sibnath, and Anutosh Chakraborty. "Activated carbon (type Maxsorb-III) and MIL-101 (Cr) metal organic framework based composite adsorbent for higher CH4 storage and CO2 capture." Chemical Engineering Journal 334 (2018): 780-788.
[69] Zhou, Xin, Wenyu Huang, Jinpeng Miao, Qibin Xia, Zhijuan Zhang, Haihui Wang, and Zhong Li. "Enhanced separation performance of a novel composite material GrO@ MIL-101 for CO2/CH4 binary mixture." Chemical Engineering Journal 266 (2015): 339-344.
[70] Zhou, Jing-jing, Kai-yu Liu, Chun-Long Kong, and Liang Chen. "Acetate-assisted synthesis of chromium (III) terephthalate and its gas adsorption properties." Bulletin of the Korean Chemical Society 34, no. 6 (2013): 1625-1631.
[71] Anbia, Mansoor, and Vahid Hoseini. "Enhancement of CO2 adsorption on nanoporous chromium terephthalate (MIL-101) by amine modification." Journal of Natural Gas Chemistry 21, no. 3 (2012): 339-343.
[72] Hu, Yingli, Wolfgang M. Verdegaal, Shu?Hong Yu, and Hai?Long Jiang. "Alkylamine?Tethered Stable Metal–Organic Framework for CO2 Capture from Flue Gas." ChemSusChem7, no. 3 (2014): 734-737.
[73] Lin, Yichao, Chunlong Kong, and Liang Chen. "Direct synthesis of amine-functionalized MIL-101 (Cr) nanoparticles and application for CO 2 capture." RSC Advances 2, no. 16 (2012): 6417-6419.
[74] Darunte, Lalit A., Aloysius D. Oetomo, Krista S. Walton, David S. Sholl, and Christopher W. Jones. "Direct air capture of CO2 using amine functionalized MIL-101 (Cr)." ACS Sustainable Chemistry & Engineering 4, no. 10 (2016): 5761-5768.
[75] Yan, Qiuju, Yichao Lin, Chunlong Kong, and Liang Chen. "Remarkable CO 2/CH 4 selectivity and CO 2 adsorption capacity exhibited by polyamine-decorated metal–organic framework adsorbents." Chemical Communications 49, no. 61 (2013): 6873-6875.
[76] Chen, Chong, Nengjie Feng, Qirui Guo, Zhong Li, Xue Li, Jing Ding, Lei Wang, Hui Wan, and Guofeng Guan. "Surface engineering of a chromium metal-organic framework with bifunctional ionic liquids for selective CO2 adsorption: Synergistic effect between multiple active sites." Journal of colloid and interface science 521 (2018): 91-101.
[77] Zhou, Zhenyu, Liang Mei, Chen Ma, Feng Xu, Jing Xiao, Qibin Xia, and Zhong Li. "A novel bimetallic MIL-101 (Cr, Mg) with high CO2 adsorption capacity and CO2/N2 selectivity." Chemical Engineering Science 147 (2016): 109-117.
[78] Zhou, Zhenyu, Baihua Cheng, Chen Ma, Feng Xu, Jing Xiao, Qibin Xia, and Zhong Li. "Flexible and mechanically-stable MIL-101 (Cr)@ PFs for efficient benzene vapor and CO 2 adsorption." RSC Advances 5, no. 114 (2015): 94276-94282.
[79] Kayal, Sibnath, How Wei Benjamin Teo, and Anutosh Chakraborty. "Prediction of phase transitions by investigating CO2 adsorption on 1% lithium doped MIL-101 (Cr) MOF with anomalous type isosteric heat of adsorption." Microporous and Mesoporous Materials 236 (2016): 21-27.
[80] Lin, Yichao, Hao Lin, Haimin Wang, Yange Suo, Baihai Li, Chunlong Kong, and Liang Chen. "Enhanced selective CO 2 adsorption on polyamine/MIL-101 (Cr) composites." Journal of Materials Chemistry A 2, no. 35 (2014): 14658-14665.
[81] Rodrigues, Maíra Andrade, Jéssica de Souza Ribeiro, Elisângela de Souza Costa, Jussara Lopes de Miranda, and Helen Conceição Ferraz. "Nanostructured membranes containing UiO-66 (Zr) and MIL-101 (Cr) for O2/N2 and CO2/N2 separation." Separation and Purification Technology192 (2018): 491-500.
[82] Jiang, Dongmei, Luke L. Keenan, Andrew D. Burrows, and Karen J. Edler. "Synthesis and post-synthetic modification of MIL-101 (Cr)-NH 2 via a tandem diazotisation process." Chemical Communications 48, no. 99 (2012): 12053-12055.