Thermodynamic Modeling Of Electrolytic Solutions of Ionic Liquids for Gas Hydrates Inhibition Applications

Authors

  • Ali Qasim Chemical Engineering Department, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 32610, Perak, Malaysia
  • Jeremy Heurtas National Superior Engineering School of Industrial Technologies, University in Pau, Pyrénées-Atlantiques, France
  • Muhammad Saad Khan Petroleum Engineering Department, Texas A&M University at Qatar, Doha, Qatar
  • Bhajan Lal CO2 Research Centre (CO2RES), Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 32610, Perak, Malaysia
  • Azmi Mohammad Shariff CO2 Research Centre (CO2RES), Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 32610, Perak, Malaysia
  • Pierre Cezac National Superior Engineering School of Industrial Technologies, University in Pau, Pyrénées-Atlantiques, France
  • Khor Siak Foo PTTEP, Level 26-30, Tower 2, Petronas Twin Towers, Kuala Lumpur City Centre, 50088, Kuala Lumpur, Malaysia
  • Jega Divan Sundramoorthy Baker Hughes (M) Sdn. Bhd, 207 Jalan Tun Razak, 50400 Kuala Lumpur, Federal Territory of Kuala Lumpur, Malaysia

DOI:

https://doi.org/10.37934/arfmts.81.2.110123

Keywords:

Gas hydrates, Hydrate Liquid Vapor Equilibrium (HLVE), Dickens and Quimby-Hunt model, Quaternary Ammonium Salts (QAS), Monoethylene glycol (MEG), Methanol

Abstract

The formation of hydrates in oil and gas transmission pipelines can cause blockage inside them and disrupt the normal flow. It may cause safety problems along with economic loss. To avoid these problems, it is necessary to have knowledge about gas hydrate formation. In this regard, hydrate liquid vapor equilibrium (HLVE) modeling can prove to be of significance as it predicts the phenomenon accurately. Dickens and Quinby-Hunt model is used to predict HLVE points. The experimental data has been obtained from open literature concerning inhibition of gas hydrates. The electrolytic binary solution mixtures of ionic liquids and quaternary ammonium salts (QAS) with commercial hydrate inhibitors have been taken into consideration. Methanol and mono ethylene glycol (MEG) are commercially used inhibitors. The gases forming hydrates include CO2, CH4 and mixed gas (CO2/CH4/N2). The experimental results are compared with the results obtained through modeling. The results show the applicability of the model as in case of QAS+MEG solution mixture hydrates with CO2, it shows a good fit. The HLVE findings by model for CH4 hydrates with EMIM-Cl+MEG solution mixture showed an average absolute error of less than 1% which is acceptable. The binary solution mixtures of NaCl+MEG, NaCl+MeOH and CaCl2+MeOH with tertiary gas mixture rich in CO2 were also modeled to find and compare the HLVE points from literature. It is found that the selected model is more suitable to be used in low pressure conditions and at high pressure, average absolute error (AAE) between experimental and modeling values is also high. It shows the suitability of the model and it can be further used in case of ionic compounds to predict hydrate inhibition behavior.

References

Mubashir, Muhammad, Yin Fong Yeong, Kok Keong Lau, and Thiam Leng Chew. "Effect of spinning conditions on the fabrication of cellulose acetate hollow fiber membrane for CO2 separation from N2 and CH4." Polymer Testing 73 (2019): 1-11. https://doi.org/10.1016/j.polymertesting.2018.10.036

Mubashir, Muhammad, Chew Thiam Leng, Lau Kok Keong, and Norwahyu Jusoh. "Study on the effect of process parameters on CO2/CH4 binary gas separation performance over NH2-MIL-53 (Al)/cellulose acetate hollow fiber mixed matrix membrane." Polymer Testing 81 (2020): 106223. https://doi.org/10.1016/j.polymertesting.2019.106223

Mubashir, Muhammad, Yeong Yin Fong, Lau Kok Keong, and Mohd Azmi Bin Sharrif. "Synthesis and performance of deca-dodecasil 3 rhombohedral (ddr)-type zeolite membrane in CO2 separation-a review." ASEAN Journal of Chemical Engineering 14, no. 2 (2015): 48-57. https://doi.org/10.22146/ajche.49708

Anderson, F. E., and J. M. Prausnitz. "Inhibition of gas hydrates by methanol." AIChE Journal 32, no. 8 (1986): 1321-1333. https://doi.org/10.1002/aic.690320810

Khan, Muhammad Saad, Bhajan Lal, Cornelius B. Bavoh, Lau Kok Keong, Azmi Bustam, and Nurhayati Bt Mellon. "Influence of ammonium based compounds for gas hydrate mitigation: A short review." Indian Journal of Science and Technology 10 (2017): 1-6. https://doi.org/10.1016/j.fluid.2017.02.011

Tonelli, Devin, Chantelle J. Capicciotti, Malay Doshi, and Robert N. Ben. "Inhibiting gas hydrate formation using small molecule ice recrystallization inhibitors." RSC Advances 5, no. 28 (2015): 21728-21732. https://doi.org/10.1039/C4RA14746D

Sloan, E. Dendy, and Carolyn A. Koh. "Clathrate hydrates of natural gases third edition." Chemical Industries-New York Then Boca Raton-Marcel Dekker Then CRC Press - 119 (2008).

Sloan, E. Dendy, Carolyn Koh, and Amadeu K. Sum. Natural gas hydrates in flow assurance. Gulf Professional Publishing, 2010.

Khan, Muhammad Saad, Bhajan Lal, Lau Kok Keong, and Iqbal Ahmed. "Tetramethyl ammonium chloride as dual functional inhibitor for methane and carbon dioxide hydrates." Fuel 236 (2019): 251-263. https://doi.org/10.1016/j.fuel.2018.09.001

Khan, Muhammad Saad, Bhajan Lal, Azmi Mohd Shariff, and Hilmi Mukhtar. "Ammonium hydroxide ILs as dual-functional gas hydrate inhibitors for binary mixed gas (carbon dioxide and methane) hydrates." Journal of Molecular Liquids 274 (2019): 33-44. https://doi.org/10.1016/j.molliq.2018.10.076

Nashed, Omar, Didar Dadebayev, Muhammad Saad Khan, Cornelius B. Bavoh, Bhajan Lal, and Azmi Mohd Shariff. "Experimental and modelling studies on thermodynamic methane hydrate inhibition in the presence of ionic liquids." Journal of Molecular Liquids 249 (2018): 886-891. https://doi.org/10.1016/j.molliq.2017.11.115

Bavoh, Cornelius B., Muhammad Saad Khan, Vennesa Johnny Ting, Bhajan Lal, Titus Ntow Ofei, Joel Ben-Awuah, Muhammad Ayoub, and Azmi Bin Mohd Shariff. "The effect of acidic gases and thermodynamic inhibitors on the hydrates phase boundary of synthetic Malaysia natural gas." In IOP Conference Series: Materials Science and Engineering, vol. 458, no. 1, p. 012016. IOP Publishing, 2018. https://doi.org/10.1088/1757-899X/458/1/012016

Partoon, Behzad, Khalik M. Sabil, and Lau Kok Keong. "Capturing carbon dioxide through a gas hydrate-based process." Chemical Engineering Transactions 45 (2015): 1867-1872.

Koh, C. A., Robin Earle Westacott, W. Zhang, K. Hirachand, J. L. Creek, and A. K. Soper. "Mechanisms of gas hydrate formation and inhibition." Fluid Phase Equilibria 194 (2002): 143-151. https://doi.org/10.1016/S0378-3812(01)00660-4

Khan, Muhammad Saad, Bavoh B. Cornelius, Bhajan Lal, and Mohamad Azmi Bustam. "Kinetic assessment of tetramethyl ammonium hydroxide (ionic liquid) for carbon dioxide, methane and binary mix gas hydrates." Recent Advances in Ionic Liquids (2018): 159-179. https://doi.org/10.5772/intechopen.77262

Sloan, E. Dendy. "A changing hydrate paradigm-from apprehension to avoidance to risk management." Fluid Phase Equilibria 228 (2005): 67-74. https://doi.org/10.1016/j.fluid.2004.08.009

Qasim, Ali, Muhammad Saad Khan, Bhajan Lal, and Azmi Mohammad Shariff. "Phase equilibrium measurement and modeling approach to quaternary ammonium salts with and without monoethylene glycol for carbon dioxide hydrates." Journal of Molecular Liquids 282 (2019): 106-114. https://doi.org/10.1016/j.molliq.2019.02.115

Qasim, Ali, Muhammad Saad Khan, Bhajan Lal, and Azmi Mohammad Shariff. "A perspective on dual purpose gas hydrate and corrosion inhibitors for flow assurance." Journal of Petroleum Science and Engineering 183 (2019): 106418. https://doi.org/10.1016/j.petrol.2019.106418

Mokhatab, S., Robert J. Wilkens, and K. J. Leontaritis. "A review of strategies for solving gas-hydrate problems in subsea pipelines." Energy Sources, Part A 29, no. 1 (2007): 39-45. https://doi.org/10.1080/009083190933988

Makogon, Yuri F. "Natural gas hydrates-A promising source of energy." Journal of Natural Gas Science and Engineering 2, no. 1 (2010): 49-59. https://doi.org/10.1016/j.jngse.2009.12.004

Sa, Jeong-Hoon, Gye-Hoon Kwak, Kunwoo Han, Docheon Ahn, Seong Jun Cho, Ju Dong Lee, and Kun-Hong Lee. "Inhibition of methane and natural gas hydrate formation by altering the structure of water with amino acids." Scientific Reports 6, no. 1 (2016): 1-9. https://doi.org/10.1038/srep31582

Ruppel, Carolyn. "Methane hydrates and the future of natural gas." MITEI Natural Gas Report, Supplementary Paper on Methane Hydrates 4 (2011): 25.

Koh, Carolyn A., E. Dendy Sloan, Amadeu K. Sum, and David T. Wu. "Fundamentals and applications of gas hydrates." Annual Review Of Chemical and Biomolecular Engineering 2 (2011): 237-257. https://doi.org/10.1146/annurev-chembioeng-061010-114152

Zerpa, Luis E., Jean-Louis Salager, Carolyn A. Koh, E. Dendy Sloan, and Amadeu K. Sum. "Surface chemistry and gas hydrates in flow assurance." Industrial & Engineering Chemistry Research 50, no. 1 (2011): 188-197. https://doi.org/10.1021/ie100873k

Kelland, Malcolm A. "History of the development of low dosage hydrate inhibitors." Energy & Fuels 20, no. 3 (2006): 825-847. https://doi.org/10.1021/ef050427x

Kelland, Malcolm A. Production chemicals for the oil and gas industry - Second Edition. CRC press, 2014. https://doi.org/10.1201/b16648

Khan, Muhammad Saad, Bhajan Lal, Lau Kok Keong, and Khalik Mohamad Sabil. "Experimental evaluation and thermodynamic modelling of AILs alkyl chain elongation on methane riched gas hydrate system." Fluid Phase Equilibria 473 (2018): 300-309. https://doi.org/10.1016/j.fluid.2018.07.003

Obanijesu, E. O., Rolf Gubner, Ahmed Barifcani, Vishnu Pareek, and M. O. Tade. "The influence of corrosion inhibitors on hydrate formation temperature along the subsea natural gas pipelines." Journal of Petroleum Science and Engineering 120 (2014): 239-252. https://doi.org/10.1016/j.petrol.2014.05.025

Gupta, Pawan, Sivabalan Sakthivel, and Jitendra S. Sangwai. "Effect of aromatic/aliphatic based ionic liquids on the phase behavior of methane hydrates: Experiments and modeling." The Journal of Chemical Thermodynamics 117 (2018): 9-20. https://doi.org/10.1016/j.jct.2017.08.037

Bavoh, Cornelius B., Omar Nashed, Muhammad Saad Khan, Behzad Partoon, Bhajan Lal, and Azmi M. Sharif. "The impact of amino acids on methane hydrate phase boundary and formation kinetics." The Journal of Chemical Thermodynamics 117 (2018): 48-53. https://doi.org/10.1016/j.jct.2017.09.001

Dickens, Gerald R., and Mary S. Quinby?Hunt. "Methane hydrate stability in pore water: a simple theoretical approach for geophysical applications." Journal of Geophysical Research: Solid Earth 102, no. B1 (1997): 773-783. https://doi.org/10.1029/96JB02941

Pieroen, A. P. "Gas hydrates?approximate relations between heat of formation, composition and equilibrium temperature lowering by "inhibitors"." Recueil Des Travaux Chimiques Des Pays?Bas 74, no. 8 (1955): 995-1002. https://doi.org/10.1002/recl.19550740808

Bavoh, C. B., B. Lal, M. S. Khan, H. Osei, and M. Ayuob. "Inhibition effect of 1-ethyl-3-methylimidazolium chloride on methane hydrate equilibrium." In Journal of Physics Conference Series, vol. 12060 (2018). https://doi.org/10.1088/1742-6596/1123/1/012060

Qasim, Ali, Muhammad Saad Khan, Bhajan Lal, Mokhtar Che Ismail, and Khairul Rostani. "Quaternary ammonium salts as thermodynamic hydrate inhibitors in the presence and absence of monoethylene glycol for methane hydrates." Fuel 259 (2020): 116219. https://doi.org/10.1016/j.fuel.2019.116219

Khan, Muhammad Saad, Cornelius B. Bavoh, Behzad Partoon, Omar Nashed, Bhajan Lal, and Nurhayati Bt Mellon. "Impacts of ammonium based ionic liquids alkyl chain on thermodynamic hydrate inhibition for carbon dioxide rich binary gas." Journal of Molecular Liquids 261 (2018): 283-290. https://doi.org/10.1016/j.molliq.2018.04.015

Nashed, Omar, Behzad Partoon, Bhajan Lal, Khalik M. Sabil, and Azmi Mohd Shariff. "Review the impact of nanoparticles on the thermodynamics and kinetics of gas hydrate formation." Journal of Natural Gas Science and Engineering 55 (2018): 452-465. https://doi.org/10.1016/j.jngse.2018.05.022

Nasir, Qazi, K. K. Lau, Bhajan Lal, and Khalik M. Sabil. "Hydrate dissociation condition measurement of CO2-rich mixed gas in the presence of methanol/ethylene glycol and mixed methanol/ethylene glycol+ electrolyte aqueous solution." Journal of Chemical & Engineering Data 59, no. 11 (2014): 3920-3926. https://doi.org/10.1021/je5008313

Richard, Anthony R., and Hertanto Adidharma. "The performance of ionic liquids and their mixtures in inhibiting methane hydrate formation." Chemical Engineering Science 87 (2013): 270-276. https://doi.org/10.1016/j.ces.2012.10.021

Keshavarz, Leila, Jafar Javanmardi, Ali Eslamimanesh, and Amir H. Mohammadi. "Experimental measurement and thermodynamic modeling of methane hydrate dissociation conditions in the presence of aqueous solution of ionic liquid." Fluid Phase Equilibria 354 (2013): 312-318. https://doi.org/10.1016/j.fluid.2013.05.007

Partoon, Behzad, Nordiyana MS Wong, Khalik M. Sabil, Khashayar Nasrifar, and Mohd Riduan Ahmad. "A study on thermodynamics effect of [EMIM]-Cl and [OH-C2MIM]-Cl on methane hydrate equilibrium line." Fluid Phase Equilibria 337 (2013): 26-31. https://doi.org/10.1016/j.fluid.2012.09.025

Bavoh, Cornelius B., Behzad Partoon, Bhajan Lal, and Lau Kok Keong. "Methane hydrate-liquid-vapour-equilibrium phase condition measurements in the presence of natural amino acids." Journal of Natural Gas Science and Engineering 37 (2017): 425-434. https://doi.org/10.1016/j.jngse.2016.11.061

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Published

2021-04-01

How to Cite

Qasim, A., Heurtas, J., Khan, M. S., Lal, B., Shariff, A. M., Cezac, P., Foo, K. S., & Sundramoorthy, J. D. (2021). Thermodynamic Modeling Of Electrolytic Solutions of Ionic Liquids for Gas Hydrates Inhibition Applications. Journal of Advanced Research in Fluid Mechanics and Thermal Sciences, 81(2), 110–123. https://doi.org/10.37934/arfmts.81.2.110123

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